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Molality Calculator

Solute given as

Sum of atomic masses, e.g. NaCl = 58.44 g/mol

Molality (mol/kg) —
Moles of solute
—
Solvent mass (kg)
—
Millimolal (mmol/kg)
—
Solute mass percent
—

Molality is the moles of solute divided by the mass of solvent in kilograms, written mol/kg or m. Dissolve 18 g of glucose (180.16 g/mol) in 500 g of water: 18 ÷ 180.16 = 0.0999 mol, and 0.0999 ÷ 0.500 kg = 0.1998 mol/kg. Unlike molarity, it does not change when the solution warms or cools.

About this tool

Molality matters wherever temperature moves: freezing-point depression, boiling-point elevation and osmotic work all use mol/kg because a mass of solvent does not expand the way a volume of solution does. Students preparing colligative-property problems and lab staff weighing out reference solutions both need it. Enter the solute either as a mass with its molar mass or directly as moles, then the solvent mass in grams or kilograms. The result shows molality to four decimals, the moles of solute, the solvent mass in kilograms, the millimolal value and, when a solute mass is known, the mass percent of the mixture. One limit: the denominator is the solvent alone, so if you only know the total mass of solution, subtract the solute mass first.

How to use it

  1. Choose how the solute is given

    Pick mass and molar mass if you weighed the solute, or amount in moles if you already know n.

  2. Enter the solute

    Type the mass in grams and the molar mass in g/mol, or the amount in mol.

  3. Enter the solvent mass

    Type the solvent mass and set the unit beside it to g or kg.

  4. Read the result

    Molality appears in mol/kg with the working listed beneath it, including the mole calculation.

Examples

58.44 g NaCl in 1 kg water

Solute given as
Mass and molar mass
Solute mass
58.44
Solute molar mass
58.44
Solvent mass
1
Solvent unit
kg

Result Molality (mol/kg): 1
Moles of solute: 1
Solvent mass (kg): 1
Millimolal (mmol/kg): 1,000
Solute mass percent: 5.521%

  1. n = 58.44 g ÷ 58.44 g/mol = 1 mol
  2. b = 1 mol ÷ 1 kg = 1 mol/kg
  3. Mass % = solute ÷ (solute + solvent) × 100 = 5.521%

One mole of sodium chloride in one kilogram of water is the textbook 1 molal solution.

18 g glucose in 500 g water

Solute given as
Mass and molar mass
Solute mass
18
Solute molar mass
180.16
Solvent mass
500
Solvent unit
g

Result Molality (mol/kg): 0.1998
Moles of solute: 0.099911
Solvent mass (kg): 0.5
Millimolal (mmol/kg): 199.82
Solute mass percent: 3.475%

  1. n = 18 g ÷ 180.16 g/mol = 0.099911 mol
  2. Solvent = 500 g ÷ 1000 = 0.5 kg
  3. b = 0.099911 mol ÷ 0.5 kg = 0.1998 mol/kg
  4. Mass % = solute ÷ (solute + solvent) × 100 = 3.475%

18 g ÷ 180.16 g/mol is 0.0999 mol; divided by 0.5 kg of water that gives about 0.1998 mol/kg.

0.25 mol in 0.5 kg solvent

Solute given as
Amount in moles
Solute amount
0.25
Solvent mass
0.5
Solvent unit
kg

Result Molality (mol/kg): 0.5
Moles of solute: 0.25
Solvent mass (kg): 0.5
Millimolal (mmol/kg): 500
Solute mass percent: Needs the solute mass

  1. Amount of solute n = 0.25 mol
  2. b = 0.25 mol ÷ 0.5 kg = 0.5 mol/kg

When the amount is already in moles, molality is a single division: 0.25 ÷ 0.5 = 0.5 mol/kg.

How it is calculated

b = n ÷ m_solvent, with n = m_solute ÷ M

b
molality, mol/kg
n
amount of solute, mol
m_solute
mass of solute, g
M
molar mass of solute, g/mol
m_solvent
mass of solvent, kg

IUPAC defines molality as the amount of solute divided by the mass of solvent. The calculator converts the solute mass to moles with its molar mass, converts a solvent mass given in grams to kilograms by dividing by 1000, then divides. Mass percent uses solute mass over solute plus solvent mass.

When not to use it

  • Use molarity instead when a recipe or titration is written per litre of solution.
  • Do not enter the total solution mass as the solvent mass.
  • For ionic solutes in colligative problems, molality alone ignores the van 't Hoff factor.

Common mistakes

  • Leaving the solvent in grams while treating the answer as per kilogram.
  • Using the molar mass of an anhydrous salt when the hydrate was weighed.
  • Confusing molality (m, per kg solvent) with molarity (M, per litre solution).

Frequently asked questions

How is molality different from molarity?

Molarity divides moles of solute by litres of the whole solution, while molality divides by kilograms of solvent only. Because volume changes with temperature and mass does not, molality stays fixed as a solution warms. For dilute water solutions near room temperature the two numbers are close, since a litre of water weighs about one kilogram.

Why do freezing-point calculations use molality?

The relation ΔT = K × b uses molality because the cryoscopic and ebullioscopic constants are defined per kilogram of solvent. For water, Kf is 1.86 °C·kg/mol, so a 0.5 mol/kg solution of a non-electrolyte freezes about 0.93 °C below pure water.

What does the unit m mean?

A lowercase m, read as molal, is shorthand for mol/kg. A 2 m sucrose solution holds 2 moles of sucrose per kilogram of water. IUPAC prefers writing mol/kg in full to avoid confusion with metres or with molar (M).

Can I use this with a solvent other than water?

Yes. The definition only needs the solvent mass, so ethanol, benzene or any other liquid works the same way. If you measured the solvent by volume, multiply by its density first to get the mass.

What if I only know the mass of the whole solution?

Subtract the solute mass from the solution mass to get the solvent mass, then enter that. For example, 110 g of solution containing 10 g of salt has 100 g of solvent, or 0.100 kg.

How do I find the molar mass of my solute?

Add the standard atomic masses of every atom in the formula. Sodium chloride is 22.99 + 35.45 = 58.44 g/mol, and glucose, C6H12O6, is 180.16 g/mol. For a hydrate, include the water molecules in the formula.

Cite this tool

Using this tool in an assignment, article or report? Copy a citation, or a link for your website.

APA

Tools Directory Editorial Team. (2026, October 17). Molality Calculator. Tools Directory. Retrieved October 27, 2026, from https://tools.milunir.com/chemistry/solutions-and-concentration/molality-calculator/

MLA

Tools Directory Editorial Team. “Molality Calculator.” Tools Directory, 17 Oct. 2026, https://tools.milunir.com/chemistry/solutions-and-concentration/molality-calculator/. Accessed 27 Oct. 2026.

Chicago

Tools Directory Editorial Team. “Molality Calculator.” Tools Directory. Last modified October 17, 2026. Accessed October 27, 2026. https://tools.milunir.com/chemistry/solutions-and-concentration/molality-calculator/.

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